Given that pure water boils at 100°C and pure toluene boils at 110.6°C, and knowing that water and toluene do not mix, what is the temperature at which an evenly mixed equimolar combination of these two liquids will exert a total pressure of one atmosphere?

Stoichiometry MCQs for PPSC, FPSC, NTS, and Pakistan government job tests. Select an option below, then read the explanation.

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Subject
Stoichiometrychemical-engineering › stoichiometry
Published
4 Mar 2019
Last updated
28 May 2026

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Explanation

Since water and toluene are immiscible, their vapor pressures add up independently. An equimolar mixture will exert a total vapor pressure of one atmosphere at a temperature between the boiling points of pure water (100°C) and pure toluene (110.6°C). Therefore, the boiling temperature of the mixture lies between 100°C and 110°C.

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